Anything that's marked like this means that you should press Ctrl-V before typing that character, as a way to enter it as a literal.
To make these stick, make sure you have ~/.viminfo being saved.
" :CC do a syntax-check on the current Perl program " :PP run the current Perl program " :PPL run the current Perl program, piped to less command! PP !PATH=.:$PATH % command! PPL !PATH=.:$PATH % | less command! CC !perl -c % 2>&1 | head -20